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2. Vat dyes dyeing process
Vat dyes do not dissolve in water, while when
reduced to be leuco salt by reducing agent under
alkaline conditions, they can dissolve in water and get
feature of immediacy with cellulose fibers, which is the
way to achieve the purpose of dyeing. Then stable shade
and good color fastness would come out via oxidation and
soaping.
2.1 Reduction of dyes
Insoluble reducing dye will change into
soluble leuco.
.Different levels of the best staining methods are
brought out according to the reduction dyes' reduction
potential and level of its immediacy to fibers.
2.2 Dye-uptake of leuco
The leuco is adsorbed by fiber and then it is
diffusing into the fiber.
It is necessary to use soft water or softened
water in dyeing process. Hereby it is suggested to add
the water softener for 1g/L to some poor quality cotton
fabric. The water softener would not only absorb
calcium, magnesium ions, but also the iron, copper ions
which are absorbed by the pipe into the dye bath, and
finally keep the solubility of leuco.
The sodium sulfate could increase the dyeing absorption
rate, and surely it is also a good promoter. So it can
be added into the dye bathes with medium or low
immediacy according to the demand.Referring to 3.13.
2.3 Leuco Oxidizing
The leuco absorbed by fiber is oxygenated and
changed into the former insoluble vat dyes, then it
colors.
Scour them in 2-3 baths with soft ware before
oxygenation, avoiding to be oxygenated with alkali.
Hydrogen peroxide is most suitable for
suspension padding, while after oxygenation, it should
be in soap boiling immediately without washing.
The sodium perborate is mild in very widely use.
It can be bathed with the next procedure (referring to
soap boiling).
2.4 Soaping treatment
The stable shade and good color fastness would
come out via soap boiling.
Through high-temperature soap boiling, the
floating color can be removed and the crystallization of
vat dyes on fabric would be enhanced, so the fastness is
increased, the stable and full color is achieved.
The soap lotion which is compounded by nonionic
and containing chelating agents plays a better role in
color light promoting. |